EXCITED STATE REACTIONS AND HETEROGENEITY OF MOLECULAR SOLUTIONS

Alexander P. Demchenko, Nikolai A. Nemkovich, Vladimir I. Tomin

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ISBN/ISSN:

978-83-7467-253-5

DOI:

Wydawnictwo:

Wydawnictwo Naukowe Uniwersytetu Pomorskiego w Słupsku

Rok wydania:

2015

Liczba stron:

274

XML:ISBN/ISSN:

ONIX MARC21

Bibliografia:

Demchenko, Alexander P.; Nemkovich, Nikolai A.; Tomin, Vladimir I.. EXCITED STATE REACTIONS AND HETEROGENEITY OF MOLECULAR SOLUTIONS. Red. . Słupsk: Wydawnictwo Naukowe Uniwersytetu Pomorskiego w Słupsku, 2015, 274 s. ISBN 978-83-7467-253-5

Bibliografia refWorks:

RT Book, Whole

SR Electronic(1)

A1 Demchenko, A.P.

A1 Nemkovich, N.A.

A1 Tomin, V.I.

T1 EXCITED STATE REACTIONS AND HETEROGENEITY OF MOLECULAR SOLUTIONS

PB Wydawnictwo Naukowe Uniwersytetu Pomorskiego w Słupsku

PP Słupsk

YR 2015

SN 978-83-7467-253-5

Bibliografia BibTex:

@Book{ 293447, author = "Demchenko, Alexander P. and Nemkovich, Nikolai A. and Tomin, Vladimir I.", editor = "", title = "EXCITED STATE REACTIONS AND HETEROGENEITY OF MOLECULAR SOLUTIONS", publisher = "Wydawnictwo Naukowe Uniwersytetu Pomorskiego w Słupsku", year = "2015", address = "Słupsk", isbn = "978-83-7467-253-5" }

Bibliografia endNote:

TY - BOOK

AU - Demchenko, Alexander P.

AU - Nemkovich, Nikolai A.

AU - Tomin, Vladimir I.

ED -

TI - EXCITED STATE REACTIONS AND HETEROGENEITY OF MOLECULAR SOLUTIONS

PB - Wydawnictwo Naukowe Uniwersytetu Pomorskiego w Słupsku

CY - Słupsk

PY - 2015

SN - 978-83-7467-253-5

ER -

Netografia (standard APA):

Demchenko, Alexander P.; Nemkovich, Nikolai A.; Tomin, Vladimir I.. EXCITED STATE REACTIONS AND HETEROGENEITY OF MOLECULAR SOLUTIONS [baza danych online] Słupsk: Wydawnictwo Naukowe Uniwersytetu Pomorskiego w Słupsku, 2015 [dostęp: 23 07 2024]. Dostęp w Ibuk Libra: https://libra.ibuk.pl/reader/excited-state-reactions-and-heterogeneity-of-molecular-solutions-alexander-p-demchenko-nikolai-293447.

Inherent peculiarities of liquid molecular systems including organic ones are fluctuations of microdensity, micropolarity and other microcharacteristics of medium owing to thermal motions of molecules and their segments. In polymer and biological ...

Więcej

ISBN/ISSN:

978-83-7467-253-5

DOI:

Wydawnictwo:

Wydawnictwo Naukowe Uniwersytetu Pomorskiego w Słupsku

Rok wydania:

2015

Liczba stron:

274

XML:ISBN/ISSN:

ONIX MARC21

Spis treści niedostępny

rowerspectralrangethanoverallspectralensemble.Suchsub-ensemblesof

luminophorsariseasaresultofselectivemonochromaticexcitationandtheir

physico-chemicalpropertiesdifferessentially,inparticular,whengroups

withlowerfrequenciesof0-0electronictransitionsareexcited.Asaresult

therehavebeenfoundremarkablespectroscopicfeaturesofpolarsolutions

whichobtainedthecommonnameoftheRed-Edgeeffects.Thesenew

achievementshavefoundextensiveapplicationsinchemistryandphysicsof

liquidstate,biophysicsandbiophotonics.Selectivespectroscopyoccupies

veryimportantplaceinstudyofmolecularsystemsespeciallyonescharac-

terizingbyheterogeneitiesoftheirspectraassuggestsstudyingpropertiesof

individualgroupsoffluorescentcenterswiththeaimtofindoutdetailfea-

turesofmembersoflargespectroscopicinhomogeneousensemble.Hence,

suchapproachbenefitsnewopportunitiesessentiallyenlargementinforma-

tivenessofspectroscopyofcomplexmoleculeswithbroadenedelectronic

spectra.Thismethodiscompetitivewithrelativelynewmethodsofsingle

moleculesspectroscopyasthathasrestrictedframesofapplicationbesides

morecomplicatedtechniqueinvolvedandthefactthatonlysomedefinite

classesofmolecularobjectscanbestudied.

ThemonographisopenedbytheChapterTheRed-EdgeEffects(byAl-

exanderDemchenko)whichpresentsgeneralintroductiontotheproblem

andthoroughlysketchespracticallyallnumerousfieldswhereselectivespec-

troscopyrevealsnewfeaturesandeffects,someofthemareoffundamental

importance.Thisisthemostcomprehensivereviewofdifferentfieldswhere

rededgeexcitationspectroscopyisappliedatthepresenttime.Therichex-

perimentalmaterialgatheredbytheauthorandtheotherresearchersfrom

differentlaboratoriesallovertheglobeservesasabaseforillustrationof

newpossibilitiesandeffectsappearingduetoheterogeneityofspectralcen-

ters,duetothermalfluctuationsofmediaandotherstructuralinhomo-

geneities.ThesecondChapter(byVladimirTomin)isdevotedtotreatment

heterogeneityofmolecularsolutionsandstudyofchargetransfer,CT,and

excitedstateinternalprotontransfer,ESIPT,reactionsinliquidsystems.The

chaptercontentsoriginalclassicalthermodynamicapproachelaboratedto-

getherwiththeco-authors,allowingtodescribethecomplexofneweffects

arisinginmolecularsystemsduetoinhomogeneityoftheirstructures.New

originalresultsinstudyofbroadeningofelectronicspectraofsolutesappear-

inginCTandESIPTstatesandeffectsarisinginsuchreactionsatselective

excitationarepresentedandanalyzed.Importantlythatselectivespectros-

copyopensgoodopportunitytoselectindividualgroupsofsoluteswithdif-

ferentratesofexcitedstatereactionsand,hence,insuchwayonecancontrol

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EXCITED STATE REACTIONS AND HETEROGENEITY OF MOLECULAR SOLUTIONS

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