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10
Fundamentalsofinfraredspectroscopy(FT-IR)...................11
(KamillaMalek,EmiliaStaniszewska-Ślęzak,KamilaKochan,KatarzynaMajzner)
1.1.Quantumdescription-modelsoftheharmonicandanharmonicoscillators..12
1.2.Normalcoordinates..............................................13
1.3.ConstructionofaFT-IRspectrometer................................15
1.3.1.
Lightsource.............................................15
1.3.2.
Interferometer...........................................16
1.3.3.
Samplechamber..........................................17
1.3.4.
Detector................................................17
20
FundamentalsofRamanscatteringspectroscopy.................19
(KamillaMalek,MałgorzataBarańska,KamilaKochan)
2.1.QuantumdescriptionofRamanscattering............................20
2.2.InstrumentationinRamanspectroscopy..............................22
2.2.1.
Laser..................................................23
2.2.2.
Samplecompartment......................................23
2.2.3.
Opticalelementsplittingthebeamofelectromagneticradiation....24
2.2.4.
Detector................................................25
3.
SpecialFT-IRtechniques.......................................26
3.1.SamplingtechniquesinFT-IRspectroscopy(PawełMiśkowiec).............26
3.1.1.
Transmissiontechnique....................................26
3.1.2.
Reflexivetechniques......................................27
3.1.2.1.Attenuatedtotalreflection,ATR.......................28
3.1.2.2.Difusereflectioninthemid-infraredrange,DRIFT.......30
3.1.2.3.Reflection-absorptioninfraredspectroscopy,IRRAS......32
3.1.3.
Photoacousticspectroscopy,PAS.............................34
3.1.4.
Infraredemissionspectroscopy,ES(IRES).....................35
3.2.FT-IRmicroscopyandimaging(EwelinaWiercigroch,KamillaMalek).........36
3.3.Vibrationalcirculardichroism(PiotrF
.J.Lipiński).......................40
3.3.1.
Chirality................................................40
3.3.2.
WhatisVibrationalCircularDichroism?......................40
3.3.3.
HowisVCDmeasured?....................................41
3.3.4.
ApplicationsofVCDspectroscopy...........................42
